Innentitelbild: A Nanoscale Molecular Switch Triggered by Thermal, Light, and Guest Perturbation (Angew. Chem. 14/2009)
Identifieur interne : 007F58 ( Main/Exploration ); précédent : 007F57; suivant : 007F59Innentitelbild: A Nanoscale Molecular Switch Triggered by Thermal, Light, and Guest Perturbation (Angew. Chem. 14/2009)
Auteurs : Martin Duriska ; Suzanne Neville ; Boujemaa Moubaraki ; John Cashion [Australie] ; Gregory Halder [États-Unis] ; Karena Chapman [États-Unis] ; Chérif Balde [France] ; Jean-François Létard [France] ; Keith Murray ; Cameron Kepert [Australie] ; Stuart Batten [Australie]Source :
- Angewandte Chemie [ 0044-8249 ] ; 2009-03-23.
Abstract
Ein kontinuierlicher Wechsel zwischen magnetischen High‐Spin‐ und Low‐Spin‐Zuständen wird durch Einstrahlen von rotem bzw. grünem Laserlicht erreicht. In der Zuschrift auf S. 2587 ff. berichten S. R. Batten et al. über ein Metallosupramolekül, bei dem durch Temperaturwechsel oder durch Einstrahlen von Licht ein Spin‐Crossover(SCO)‐Schalten möglich ist. Das SCO‐Verhalten hängt zudem von der Gegenwart und der Art eingeschlossener Lösungsmittelmoleküle in der porösen Kristallstruktur ab.
Url:
DOI: 10.1002/ange.200990068
Affiliations:
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In der Zuschrift auf S. 2587 ff. berichten S. R. Batten et al. über ein Metallosupramolekül, bei dem durch Temperaturwechsel oder durch Einstrahlen von Licht ein Spin‐Crossover(SCO)‐Schalten möglich ist. 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